This isn't something that I get asked, but then we have only 240/415V and not the variety of systems you use.
I do sometimes get asked to explain 3-phase, though. Except for isolated single properties, all domestic distribution is 3-ph 4-w wye with homes tapped off one phase, so in rural areas with overhead lines I sometimes get the question: "Why are there four wires up there?" Some folks who work in commercial buidings and see the 415V stickers ask how 415 relates to 240V.
I've found that many people can understand the concept of a "back-to-back" arrangement like your domestic 120/240, but start mentioning the sq. root of 3 and they're lost.