Another time you'd use white as a hot is a 240V circuit.
Unless, of course, you want to run 12/3 (unneeded expense)and have an unused white at the load. You would/should have to land the white at the panel though, if you did that. I have seen 6/2 WG that has black and red wires (there is some in my house), but I have never seen it for sale myself. So, I don't know if it is even available anymore.