Does 2005 NEC T310.15(B)(6) allow 4/0 Al for service and feeder, or is that trumped by the manufacturer’s label [Use 60/75C conductors], which would require 250 kcmil?
The safe bet is always to ask your AHJ as theirs is the only opinion that matters, but I concur with Greg, 310.15(B)(6) requires 4/0, and specifically states you don't have to go larger. 310.16 does not apply to this cable.