Briselec,
You are absolutely right mate.
The Grey stuff is u-PVC (UV-stabilised PVC).
The Orange stuff is Chemically resistant PVC.
I have never ever seen Orange PVC conduit being painted and I mean there is HEAPS of it used over here, a lot of it by Power Companies.
I just read in AS/NZS 3000, it is supposed to be painted if not UV stabilised.
You learn something new every day.